Both SSC and HIC are two types of metal failures
involved in Pipes with Hydrocarbon service , where there are
substancial amount of H2S and Hydrogen ion concentration.
Sulphide Stress Cracking
is a Brittle Failure by Cracking
under the combined action of Tensile stress and Corrosion
in the presence of Water and H2S.
NACE standard MR-0175 says:
Sulphide Stress Cracking (SSC) is affected by following factors:
1) Metal Chemical composition, Strength, heat Treatment (Hardness)
and microstructure.
2) Hydrogen Iron Concentration (PH) of the environment
3) H2S Concentration and total pressure
4) .Total tensile stress (Applied + Residual)
5)Temperature
6) Time.
Hence,
Any Material has got a limiting value of Hardness number
(HRC 22 Maximum; even Stainless Steels have to meet this requirement)
if it is to be used under SSC -prone environments.
Hydrogen Induced Cracking.
Paltes and simillar rolled items which are used as the raw material
for Pipe and Pipe fittings have
Fiber structure along the Rolled Directions.
Under Service Conditions with high Concentration of Hydrogen Ions,
there is a chance of
Cracks forming along these fibers and many such Cracks running
parallel may Join
among themselves forming a series of Cracks.
Inorder to avoid this possibility and to ensure that there won't be
any such Crack for a given material,
we may have to test the material for HIC, before it is used in such
Environments.
HIC requirements are as given below:
- Material shall be either HIC tested as per TM-0284
OR
shall satisfy the following chemical composition
Carbon equivalent calculated as CE=C+ Mn/6 + (Cr+Mo+V)/5 +
(Ni+Cu)/15 shall be 0.43% maximum for all items
- Max. Mangenese 1.35%
- Max. sulphur 0.005%
- Max. Calcium 0.0065%
HIC testing, as per TM-0284 shall be conducted using Either
Solution A
OR
synthetic sea water solution-B (Well explained in TM-0284)
and the acceptance criteria are as follows
a) CLR -15% max
b) CTR -8% max
c) CSR -1.5% max and surface blistering shall be acceptable
See, the Requirements which we have asked for ASTM A516 Grade 70
Plates (Fabricating SAW Pipes) :
C.S Plates will be HIC tested as per NACE TM 0284 using test
solution A. Acceptance norms for
HIC test results shall be as follows :
• Maximum individual crack length in any section not to exceed 5 mm
• Crack Length (CLR) : not to exceed 15%
• Crack Thickness Ratio (CTR) : not to exceed 5%
• Crack Sensitivity Ratio (CSR) : not to exceed 1.5%
Above criteria shall apply to average ratios for 3 examined
sections from one specimen.
Surface blistering is acceptable.
In case the material is acceptable as per the above requirements,
there is no harm in using such
materials.
Regards,
Balakrishnan
- In PipingDesign@yahoogroups.com, "Bruce Bullough"
<bbullough@s...> wrote:
> Mike and Chris both have part of the HIC picture (although this is
a
> subject very difficult to "prove" a mechanism in). Essentially
what
> happens is that the hydrogen atom, being very small and mobil,
works
> into the crystal structure, and either 1) stresses a previously
strong,
> stable, crystal, leading to failure at the smallest level of
crystal or
> 2) forces a change in the crystal structure (i.e., from a BCC to a
FCC
> or other combinations), resulting in a material change (austenitic
to
> ferritic?), in that particular crystal or region of crytals, and
often
> releasing energy that induces changes adjacent to it.
>
> I did a fair amount of study on hydrogen formation back in my nuke
days.
> Some level of hydrocarbon cracking or even water hydrolysis
happens all
> the time. Conditions aggravate it. Some materials are apparently
> catalysts to inducing it.
>
> The mechanisms of SIC are quite different. A good reference on it
is
> "Corrosion handbook" by HH Uhlig.
>
> ... Bruce D. Bullough ...
> Sebesta Blomberg & Associates, Inc.
> 2381 Rosegate
> Roseville, MN 55113 USA
> + 651-459-6659
> www.sebesta.com
>
>
> -----Original Message-----
> From: Michael Waugh [mailto:mike@w...]
> Sent: Thursday, May 13, 2004 8:31 PM
> To: <a href="/group/PipingDesign/post?postID=Z1TDGzA-2znBsVKbso4SFjog1d-p4VwCRQXyQiTj9aWybb-SDy8e0G6r_zy-BUh96JZ5MLXDdWglbmt1jN9K8w-OgQlN">PipingDesign@yahoogroups.com</a>
> Subject: RE: [PipingDesign] Cracking [text][bcc][faked-from][bayes]
>
> Rakeesh:
>
> It has been some time since I visited this subject, but I'll stick
my
> neck out anyhow. Hydrogen Induced Cracking (HIC) and Sulphur
Induced
> Cracking are a result the formation of hydrogen ions formed through
> various means in the material. Hydrogen ions will react with the
> material, I believe causing the formation of various acids, metal
oxides
> and sulphates etc. The chemistry here is quite vast but are largely
> dependent on the many conditions, heat, water, steam, pH etc that
you
> encounter in processes.
> Relatively speaking, you cannot prevent it from occurring, it will
> occur.
> You can only go to higher cost materials, lined piping,
anticorrosion
> devices to reduce the likelyhood of it causing failures in your
> processes.
>
> Mike
>
>
>
>
> -----Original Message-----
> From: Rakesh Patil [mailto:rpa@l...]
> Sent: Thursday, May 13, 2004 10:59 PM
> To: <a href="/group/PipingDesign/post?postID=Z1TDGzA-2znBsVKbso4SFjog1d-p4VwCRQXyQiTj9aWybb-SDy8e0G6r_zy-BUh96JZ5MLXDdWglbmt1jN9K8w-OgQlN">PipingDesign@yahoogroups.com</a>
> Subject: RE: [PipingDesign] Cracking [text][bcc][faked-from][bayes]
>
>
> Dear Bruce,
>
> Thanks for your resonse. I have a background of material science.
But
> when I checked HIC from my superiors, I found some controversy.
One told
> me that it happens when hydrocarbon flows in CS pipes due to
formation
> of
> CH4 which generally occurs at welded joints and results in a crack.
> whereas another told, it happens when a fluid (hydrocarbon) passing
> through pipe enters inside the gaps between bonds (metal
composition)
> which forms a crack after certain period.
>
> so can you please suggest me which one is correct? I have not
searched
> for it on net but will do it simultaneously. About Sulphur
Cracking, I
> am not getting anything. can you please suggest me any paper or
> literature available on the same.
>
> cheers,
> rakesh
>
>
>
>
>
>
>
>
> Rakesh:
>
> This is rather complex and not conducive to an e-mail, unless you
want
> to limit the discussion to "it's bad" and "use the right material
for
> the service to avoid it". I have corrosion and materials texts
and took
> courses on solid-phase chemistry and materials science of
corrosion to
> get a basic understanding. Have you done thorough on-line searches
> (like Google) to get some basic information? Do you have a
background
> in solid-phase chemistry and material science?
>
> ... Bruce D. Bullough ...
> Sebesta Blomberg & Associates, Inc.
> 2381 Rosegate
> Roseville, MN 55113 USA
> + 651-459-6659
> www.sebesta.com
>
>
> -----Original Message-----
> From: Rakesh Patil [mailto:rpa@l...]
> Sent: Wednesday, May 12, 2004 8:44 PM
> To: <a href="/group/PipingDesign/post?postID=Z1TDGzA-2znBsVKbso4SFjog1d-p4VwCRQXyQiTj9aWybb-SDy8e0G6r_zy-BUh96JZ5MLXDdWglbmt1jN9K8w-OgQlN">PipingDesign@yahoogroups.com</a>
> Cc: <a href="/group/PipingDesign/post?postID=Z1TDGzA-2znBsVKbso4SFjog1d-p4VwCRQXyQiTj9aWybb-SDy8e0G6r_zy-BUh96JZ5MLXDdWglbmt1jN9K8w-OgQlN">PipingDesign@yahoogroups.com</a>
> Subject: [PipingDesign] Cracking [text][bcc][faked-from][bayes]
>
> Hi All,
>
> Can anybody guide me about Hydrogen Induced Cracking (HIC) and
Sulphur
> Induced Cracking. What is the basic concept of it and How it can be
> tested and rectified.
>
> regards,
> rakesh
>
>
>
> [Non-text portions of this message have been removed]
>
>
>
>
> =========================================
> PipingOffice - Excel Spreadsheets for Piping Calculations
> <a href="http://www.pipingoffice.us/">http://www.pipingoffice.us/</a>
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>
> Yahoo! Groups Links
>
>
>
>
>
>
>
>
>
>
> =========================================
> PipingOffice - Excel Spreadsheets for Piping Calculations
> <a href="http://www.pipingoffice.us/">http://www.pipingoffice.us/</a>
> Main site: <a href="http://www.pipingdesign.com">http://www.pipingdesign.com</a>
>
> Yahoo! Groups Links
>
>
>
>
>
>
>
>
> [Non-text portions of this message have been removed]
>
>
>
>
> =========================================
> PipingOffice - Excel Spreadsheets for Piping Calculations
> <a href="http://www.pipingoffice.us/">http://www.pipingoffice.us/</a>
> Main site: <a href="http://www.pipingdesign.com">http://www.pipingdesign.com</a>
>
> Yahoo! Groups Links
>
>
>
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> =========================================
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Received on Mon May 17 16:05:00 2004